"""Original solution diagram; Python 3.14, matplotlib 3.10, numpy 2.3. Run from the mirrored media directory: PNG basename is written to cwd. """ from pathlib import Path import sys sys.path.insert(0,str(Path(__file__).resolve().parents[2])) import numpy as np import matplotlib matplotlib.use('Agg') import matplotlib.pyplot as plt from tools.chemistry_diagram import atom,bond,ring,curly,flow,finish,save,wedge,BLUE,ORANGE fig,axs=plt.subplots(3,1,figsize=(10,7));fig.subplots_adjust(top=.91,bottom=.04,hspace=.55) rows=[('1 · Insertion into Hf–Ar','Ar–CH₂–CH(Hf)–CH₂OEt','The Hf–Me bond is still present.'),('2 · β-Alkoxide elimination','Ar–CH₂–CH=CH₂ + Hf–OEt','C–O cleavage is coupled to C=C formation.'),('3 · Tethered alkene inserts into Hf–Me','Ar–CH₂–CH(Hf)–CH₂Me','Second allyl ethyl ether binds through O; it remains intact.')] for ax,(title,s,note) in zip(axs,rows): ax.axis('off');ax.set_title(title,loc='left',fontsize=13,color=BLUE);ax.text(.5,.6,s,ha='center',fontsize=19);ax.text(.5,.15,note,ha='center',fontsize=11) fig.suptitle('Atom-balanced route to the enlarged chelate of G',fontsize=15) save(fig,Path(__file__).with_suffix('.png').name)