"""Original solution figure; tested with Python 3.14.4. Dependencies: NumPy 2.3.5 and Matplotlib 3.10.7 (root pyproject.toml). Writes its PNG basename into the current working directory. """ from pathlib import Path import numpy as np import matplotlib matplotlib.use("Agg") import matplotlib.pyplot as plt plt.rcParams.update({"font.size":10,"figure.facecolor":"white","axes.facecolor":"white","savefig.facecolor":"white","axes.spines.top":False,"axes.spines.right":False}) g,w=np.polynomial.legendre.leggauss(180) def cv(t): upper=min(1/t,70);x=(g+1)*upper/2 f=x**4*np.exp(-x)/(-np.expm1(-x))**2 return 3*t**3*np.dot(w*upper/2,f) t=np.geomspace(.001,2.5,650);val=np.array([cv(z) for z in t]) fig,ax=plt.subplots(1,2,figsize=(9,3.6),layout="constrained") ax[0].plot(t,val,color="#1565a8",lw=1.8) ax[0].axhline(1,color=".5",ls="--",lw=1) ax[0].set(xlim=(0,2.5),ylim=(0,1.08),xlabel=r"$T/\Theta_D$",ylabel=r"$C_V/(3Nk_B)$",title="Approach to the Dulong–Petit limit") mask=t<.2 ax[1].loglog(t[mask],val[mask],color="#1565a8",lw=1.8,label="Debye integral") ax[1].loglog(t[mask],4*np.pi**4/5*t[mask]**3,color="#ca6720",ls="--",lw=1.5,label=r"low-temperature $T^3$ law") ax[1].set(xlabel=r"$T/\Theta_D$",ylabel=r"$C_V/(3Nk_B)$",title="Low-temperature cubic behaviour") ax[1].legend(frameon=False,fontsize=9) for a in ax:a.grid(alpha=.15) fig.savefig(Path(__file__).with_suffix('.png').name,dpi=135)