Crystal detector
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The first diodes. These were apparently incredibly unreliable, especially for portable radios, as you had to randomly search for the best contact point you could find in a random polycrystalline material!!
And also quality was highly dependant on where the material was sourced from as that affected the impurities present in the material. Later this was understood to be an issue of doping.
It was so unreliable that vacuum tube diodes overtook them in many applications, even though crystal detectors are actually semiconductor diodes, which eventually won over!
For a long time, before artificial semiconductors kicked in, people just didn't know the underlying physical working principle of these detectors. What I cannot create, I do not understand basically.