Alkoxy radical (source code)

= Alkoxy radical
{title2=$\mathrm{RO}^{\bullet}$}

An <alkoxy radical> has the form $\mathrm{RO\cdot}$, with an unpaired electron associated with oxygen. It differs from the closed-shell alkoxide anion $\mathrm{RO^-}$.

Hydrogen abstraction and carbon-carbon bond fragmentation are possible reaction pathways depending on the attached group and environment. Distinguishing radical character from negative charge is essential when interpreting how such an oxygen-centered species reacts.