The closed shells have , so only the two equivalent p electrons matter. Their addition of angular momentum allows and , subject to the Pauli exclusion principle. Interchanging two orbital states has sign : even L is spatially symmetric and needs the antisymmetric spin singlet; odd L is spatially antisymmetric and needs the symmetric spin triplet. Thus the allowed LS terms of a p-squared configuration are , and .
In LS coupling, . The complete list of term symbols is thereforeThey contain magnetic substates, exhausting the antisymmetric two-electron space. All have even spatial parity, since each p orbital is odd.
For two equivalent electrons, antisymmetry permitsTheir states exhaust . Hund's rules first maximize spin, then orbital angular momentum; the less-than-half-filled shell puts the smallest lowest. Hence the ground level is . This is the allowed LS terms of a p-squared configuration.[ref]
Energy Levels of Neutral Carbon by National Institute of Standards and Technology. Ground configuration2s²2p² and its³P,¹D,¹S levels