Amide bond rotation
= Amide bond rotation
Interconversion of amide rotamers requiring loss of favourable nitrogen–carbonyl overlap near a twisted transition region. Solvation can change the barrier relative to the starting planar amide.
= Amide bond rotation
Interconversion of amide rotamers requiring loss of favourable nitrogen–carbonyl overlap near a twisted transition region. Solvation can change the barrier relative to the starting planar amide.