Landau damping is the collisionless decay of a plasma wave through resonant energy exchange with particles whose velocity is close to the wave's phase velocity . Particles slightly slower than the wave tend to gain energy from it; particles slightly faster can give energy to it. For the decreasing resonant part of a Maxwell-Boltzmann distribution, the net transfer is from the wave to the electrons, so the wave amplitude decays.
In the linear Vlasov equation description this is collisionless phase mixing, not a requirement for frequent particle collisions. Fine-scale structure develops in the velocity dependence of the perturbation even while the macroscopic electric field decreases. The resonant contribution to the growth rate has the sign of at a positive wave phase velocity: a negative slope produces damping, whereas a sufficiently positive slope can drive an instability. A population comparison must be local to the resonance; merely counting all particles faster and slower than the wave is not the criterion.