For the complex scalar field, the canonical momenta are and . Split . The interaction picture is obtained from the Schrödinger picture by and , choosing a common time origin. The fields therefore obey the free Klein-Gordon equation, while the states evolve through . The canonical quantization of a complex scalar field gives
The adjoint expansion contains and . Particle and antiparticle modes are independent; their nonzero commutators are
All cross-species commutators, and all pairs of creation operators or of annihilation operators, vanish. These formulas reproduce and the remaining vanishing equal-time commutators.
There are no derivative interactions, so the interaction Hamiltonian is . Differentiating the interaction picture state gives . Its time-evolution operator satisfies
Iteration gives ordered integration regions . Each is of the full region with a time-ordered product, yielding the Dyson series
With the usual asymptotic scattering prescription, taking and proves
Time ordering is essential because different interaction Hamiltonians need not commute.
At first order, use the connected tree scattering amplitude, equivalently the normal-ordered quartic vertex with the vacuum and one-particle mass contributions removed. This qualification matters if the local product is interpreted literally without normal ordering: single-vertex tadpole diagrams and vacuum diagrams are not the requested connected two-particle amplitude. The complex scalar quartic contact vertex is obtained from
In a fully connected matrix element, an incoming particle and outgoing antiparticle attach to the two factors; an outgoing particle and incoming antiparticle attach to the two factors. Each pair has two assignments, giving . The external relativistic normalization of a one-particle state cancels each mode measure: for example and . Consequently the connected integrand is , and
Thus the invariant connected amplitude is
The Dirac delta function expresses four-momentum conservation.
For the identity contribution, commute through and independently through ; all terms leaving a creation operator against the left Fock vacuum or an annihilation operator against the right Fock vacuum vanish. Hence
There is no exchange term between the two distinct particle and antiparticle species.