Choose a coordinate measured from the sphere centre towards increasing distance from the block, so an atom in the sphere is at height . Summing the atom–block potential energy with the sphere's number density gives
For , a uniformly valid Taylor series over the sphere is
The odd moments vanish by reflection symmetry. The sphere volume is , and its second moment is
Consequently
The first finite-radius correction is therefore . There is no relative correction because the first moment about the centre is zero. The leading term is just the number of sphere atoms times the potential at its centre; the correction increases the attraction because the nearer atoms contribute more strongly than the farther atoms lose.
This is the far-field sphere-plane dispersion energy, with Hamaker constant . It must be distinguished from the near-contact sphere-plane dispersion force, whose small parameter is the surface gap divided by the radius. Here is explicitly the centre-to-plane distance.