Let the medium's autocorrelation function of a random field and power spectrum use the explicit convention
Since , only the linear term in is needed to obtain the cross-section through second order:
Squaring and taking the expectation gives
This is the finite-volume formula in the Born approximation for scalar wave scattering; the zero mean of does not make its squared scattered amplitude vanish. For a jointly centered Gaussian random field, the third-order contribution is zero, so the next perturbative contribution is fourth order when that expansion is valid.
Introduce the overlap volume . Changing variables rewrites the double integral as
When the linear dimensions of a regular scattering volume are large compared with the correlation length, and is integrable, over the significant covariance range. This gives the finite-volume random scattering spectrum result
There are two distinct approximations here: the weak-scattering expansion in and the negligible-boundary-overlap approximation in the volume-to-correlation-scale ratio. If instead denotes the power spectrum of the index fluctuation , then and the external factor is absorbed into .
Statistical homogeneity alone allows an anisotropic spectrum, so its argument is generally the vector . If statistical isotropy is additionally assumed, depends only on
The scalar notation is valid in that isotropic case. For the alternative convention , the bulk formula is . Changing the sign of the scattering vector does not change the spectrum of a real stationary scalar field; changing the Fourier transform normalization does change the displayed factors. Both conventions have therefore been stated explicitly.