Past exam of the chemistry B course of the University of Cambridge 2023 Paper 2 B7 b i Solution 2026-10-20
The neutral product is cis-, and the displaced material is six waters per nickel:The two phosphorus donors of dppe chelate the same metal, forcing adjacent donor positions. The diamagnetism identifies a square-planar, paired Ni(II) centre rather than a tetrahedral high-spin centre. Its valence count is electrons. The reaction is ligand substitution, not reduction of Ni(II).