Part c gives the integral representation
The integrand vanishes on the diagonal . Thus the assumed off-diagonal Peskun ordering implies
for every .
On the mean-zero subspace, the variational characterization of the spectral gap of a positive reversible kernel is
It follows immediately that
Equivalently, the energy inequality says in the Löwner order on . Positivity permits the operator monotonicity of the square root and hence ; the spectral representations in the question identify the top spectral values and give the same gap inequality.
Put . The operator inequality and the operator monotonicity of logarithm give, on the support of ,
Consequently,
The corresponding inequality from yields
Adding these inequalities and using proves the entropy bound for a binary mixture:
Singular states follow by adding a positive multiple of the identity and taking a limit; the endpoint cases use .
The two forms of found in part (i) give
Therefore, in the Löwner order,