Past exam of the quantum condensed matter course of the University of Cambridge 2008 Section A A3 f Solution Created 2026-10-18 Updated 2026-10-20
Under a step stress, the Maxwell spring extends immediately by , while the dashpot adds . Hence , and the microrheology of a Maxwell fluid relation givesThis idealized overdamped relation describes an elastic plateau followed by long-time diffusion. Its nonzero extrapolated intercept is not the actual displacement variance at exactly zero lag, which is zero. Inertia or fast solvent relaxation must resolve the initial rise; those processes were omitted from the ideal spring-dashpot model.
A creep experiment applies a small step of stress and holds it constant while recording strain. For , the series spring jumps by and the dashpot subsequently flows at constant rate . The creep compliance is thusUsing the stipulated effective stress and strain substitutions givesOn linear axes the model is a straight line of positive intercept and slope . On logarithmic axes it has an approximate elastic plateau for and slope one for , within the time window where the continuum approximation applies. The long-time slope is with , agreeing with the Stokes–Einstein relation.
There is an essential zero-lag convention. A literal lag displacement has . The nonzero intercept above is the spring-compliance extrapolation of the idealized microrheology of a Maxwell fluid, after unresolved solvent or inertial transients. It must not be interpreted as an instantaneous finite physical displacement at exactly zero lag. The stated mesh condition motivates a continuum probe response; quantitative use is more reliable for than merely .
Maxwell probe displacement
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