= Solution
The fast family is \b[NO$_3$ plus N$_2$O$_5$]. Put $x=[\mathrm{NO_3}]$, $y=[\mathrm{N_2O_5}]$, and freeze the supplied parent <concentrations> while defining
$$
S=k_2[\mathrm{NO_2}][\mathrm O_3],\quad a=k_6[\mathrm{NO_2}][\mathrm M],
\quad b=k_7,\quad c=k_8[\mathrm{H_2O}],\quad
d=k_4[\mathrm{NO}]+k_5[\mathrm{NO_2}].
$$
The two equations are $\dot x=S-(a+d)x+by$ and $\dot y=ax-(b+c)y$. Their stationary solution is
$$
\boxed{x=\frac{S}{d+ac/(b+c)}=3.09\times10^6\,\mathrm{molecules\,cm^{-3}}},
\qquad y=\frac{ax}{b+c}=7.02\times10^8\,\mathrm{molecules\,cm^{-3}}.
$$
Here $a=15.67$, $b=0.0690$, $c=3.84\times10^{-7}$ and $d=1.919$ in inverse seconds; $S=5.93\times10^6\,\mathrm{molecules\,cm^{-3}s^{-1}}$. Reversible storage must not be counted as permanent family loss: only the $ac/(b+c)$ term represents the association route followed by <hydrolysis>.
Closed-family interconversion has $\tau_{\rm eq}=1/(a+b)=0.0635\,\mathrm s$. Including the supplied losses, the two linear relaxation times are approximately \b[$0.0566\,\mathrm s$ and $133\,\mathrm s$], from the <eigenvalues> of $\begin{pmatrix}a+d&-b\\-a&b+c\end{pmatrix}$. Fast exchange is therefore well separated from the slower total-family adjustment. However, NO is consumed by <ozone> on $1/(k_1[\mathrm O_3])\simeq59.8\,\mathrm s$, comparable to and shorter than the family relaxation. Thus the quoted stationary <concentration> is justified for a maintained background or a sufficiently slowly varying quasi-stationary environment; it is not automatically reached in an isolated parcel initialized with the supplied composition. NO auto-oxidation is negligible at this <concentration>. Additional organic losses of NO$_3$, if present, would need to be added to the model.
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