Solution
= Solution
Read the potential labels rather than the alphabetical order: \b[b], the less negative event, is $\mathrm Q+e^-\rightleftharpoons Q^{\bullet-}$; \b[a], the more negative event, is $\mathrm Q^{\bullet-}+e^-\rightleftharpoons Q^{2-}$. These are the first and second reductions respectively, with the reverse branches giving the corresponding oxidations. The second electron is harder to add to an already negatively charged species.