Solution
= Solution
The <ideal gas free energy> contributes $-Nk_BT\log V$. With $V=4\pi r^3/3$ and surface energy $4\pi tr^2$, the radius-dependent free energy is therefore
$$
F(r)=-Nk_BT\log V+4\pi tr^2+\text{constant}.
$$
For equilibrium against external <pressure> $P_0$, minimize $F+P_0V$.