For an axial spin Hamiltonian with K, the minima are . The highest levels along the reversal ladder are the doublet. Henceabout 1.25 kJ mol or 12.9 meV per molecule. Using would incorrectly put a half-integer spin at a nonexistent level. Transverse anisotropy and quantum tunnelling of magnetization can create faster relaxation pathways, so this axial ladder barrier need not equal an experimentally fitted effective barrier.