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For $n\ge 0$, putEach $S_n$ is closed, the hypothesis gives $\mathbb{R}={\bigcup }_n{S}_n$, and $E_n\subset E_{n+1}$ because a function that vanishes on an open set has derivative zero there.

The open setis dense. Indeed, inside any nonempty open interval choose a nondegenerate closed subinterval $J$. The complete metric space $J$ is covered by the closed sets $J\cap S_n$, so the Baire's theorem makes one of them contain a relative open interval, which lies in some $E_n$.

On each connected component $I$ of $\Omega$, the function $F$ is one polynomial. To see this, any compact subinterval $K\subset I$ is covered by the increasing family $(E_n)$. A finite subcover therefore gives $K\subset E_N$ for some $N$, and $F^{(N)}=0$ on $K$. Hence $F$ is polynomial on $K$; overlapping compact intervals force these polynomials to agree throughout $I$.

Let $D=\mathbb{R}\setminus \Omega$. This closed set has no isolated points. Otherwise, on the two sides of an isolated point $x$, $F$ would equal polynomials. Smoothness makes all their one-sided derivatives agree at $x$, so the two polynomials are identical and extend across $x$. Some derivative would then vanish on a neighborhood of $x$, contrary to $x\in D$.

Suppose that $D$ is nonempty. It is complete andis a countable closed cover. A second application of Baire's theorem gives an index $k$ and an open interval $U_0$ such thatChoose $x_0\in D\cap U_0$ and a bounded open interval $U$ centred at $x_0$ whose closure lies in $U_0$.

Because $D$ has no isolated points, every $x\in D\cap U$ is approached by distinct points of $D\cap U$. Difference quotients first give $F^{(k+1)}(x)=0$, and induction gives

No component of $\Omega$ meeting $U$ can cross $x_0$, so it has an endpoint in $D\cap U$. If its polynomial had degree $d\ge k$, then its $d$th derivative would approach a nonzero constant at that endpoint, contradicting the preceding display. Its degree is therefore less than $k$, so $F^{(k)}$ also vanishes on the part of that component in $U$. We conclude that $F^{(k)}=0$ throughout $U$, which says $U\subset E_k\subset \Omega$ and contradicts $D\cap U\ne \varnothing$.