The first derivative of a scalar is a covector, so
Commuting partial derivatives and the torsion-free connection give , the symmetric Hessian of a scalar field. Its next covariant derivative is
In particular, tensor index symmetrization over adds nothing: . This does not make the third index interchangeable with the first two. Applying the lower-index Ricci identity to the covector yields the requested tensor index antisymmetrization:
Parentheses and brackets include the usual averaging factors. To make the remaining symmetry explicit, let . Since the first two derivative indices are already symmetric,
The two commutator identities give and . Thus the third covariant derivatives of a scalar can also be written
The right-hand side displays exactly the obstruction to total symmetry. At a point where the scalar gradient vanishes, or where these curvature contractions vanish, the third derivative is totally symmetric.
For the final contraction use . The arbitrary-valence formula gives
The Ricci tensor of the Levi-Civita connection is symmetric, whereas the last factor is antisymmetric. Their contraction is zero, proving
No symmetry of was assumed. This double divergence of a contravariant tensor identity uses the metric-compatible connection of general relativity: zero torsion alone for an arbitrary affine connection does not guarantee a symmetric Ricci tensor and would not suffice for this final step.