For the common -axis zinc-blende GaAs wire, a representative cross-section is a faceted hexagon with low-index sidewalls, often described by -type facets. The threefold crystallographic symmetry of a polar direction can make alternate facets inequivalent, so triangular or truncated-triangular sections are also possible. The zinc-blende label alone does not fix a unique hexagon: growth direction, termination, twins, surface chemistry and kinetic facet selection also matter.
The accompanying sketch shows a representative faceted section rather than a circular cylinder. Facets that advance slowly in their normal direction tend to remain exposed, so a kinetic growth shape need not be an equilibrium Wulff shape.
A simple cause of tapering is continued radial vapor–solid growth on sidewalls while the tip grows axially. A lower wire segment has been exposed to precursors for longer than a segment formed near the end of growth. For a roughly constant radial growth speed , its radius gains about , giving a larger base. Substrate-fed species, changing catalyst size and droplet wetting can also contribute. Tapering is not proof that the original VLS droplet was wider at every earlier stage.