Template-directed ring-closing metathesis and ring-opening metathesis polymerization of functionalized dienes by Robert H. Grubbs and others 2026-10-20
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US6080826A, original inventors Robert H. Grubbs, Michael J. Marsella and Heather D. Maynard. Table 1 reports template effects on cyclic-polyether formation; the discussion explicitly identifies a 14-membered ring. Only the nonbiological chemical evidence is used here.
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Template-Directed Ring-Closing Metathesis: Synthesis and Polymerization of Unsaturated Crown Ether Analogs by Michael J. Marsella and others 2026-10-20
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Primary chemical study of lithium-templated ring-closing metathesis and related unsaturated polyether formation, Angewandte Chemie International Edition in English 36, 1101–1103.
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