= Concentration polarization
{wiki=Concentration_polarization}
Concentration polarization is a phenomenon that occurs in electrochemical systems where there is a difference in concentration of reactants or products in a solution, typically near the interface of an electrode. This effect can impede the rate of electrochemical reactions and is predominantly observed in systems like batteries, fuel cells, and electrolyzers. In more detail, concentration polarization arises when the rate of mass transfer of reactants to the electrode surface cannot keep up with the rate of the electrochemical reaction that consumes these reactants.
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