= Selection rule
{wiki=Selection_rule}
Selection rules are criteria or guidelines that dictate the allowed or forbidden transitions between quantum states in quantum mechanics and spectroscopy. These rules are used to determine which transitions can occur during processes such as electronic, vibrational, or rotational transitions in molecules, as well as transitions involving photons, such as in absorption or emission of light. In the context of quantum mechanics, selection rules are derived from the intrinsic symmetries of quantum systems and are often associated with changes in certain quantum numbers.
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