 Band nonparabolicity

Band nonparabolicity is the departure of an energy band's dispersion relation from a quadratic function of crystal momentum near an extremum. A parabolic isotropic approximation writes $E={\hslash }^2{k}^2/(2m_b)$, measuring $E$ from the band edge. Band coupling can make the apparent effective mass depend on energy, especially when the separation from another band is small.^[ref]

A useful isotropic model iswhere $\alpha$ has units of inverse energy. A simple two-level illustration explains the extra factor: the eigenvalue above zero of a matrix with diagonal entries $0,-E_g$ and real off-diagonal entry $Pk$ satisfies $E(E+E_g)=P^2{k}^2$. Dividing by $E_g$ gives $\alpha =1/E_g$ and ${\hslash }^2/(2m_b)=P^2/E_g$. Real materials require a more detailed multiband model, including the appropriate symmetries and spin-orbit coupling.

Differentiating the model gives the group velocity and a momentum-to-velocity mass:This mass is distinct from the mass obtained from the local second derivative of $E(k)$. For $\alpha >0$, a state with parabolic estimate ${\hslash }^2{k}^2/(2m_b)=1/\alpha$ instead has $E=(\sqrt{5}-1)/(2\alpha )$. The energy grows more slowly than the band-edge parabola predicts. Evan O. Kane's 1957 InSb calculation connected such nonparabolic band coupling with measured optical absorption and cyclotron resonance data.^[ref]