 Central delta barrier in a symmetric infinite well

Inside walls at $\pm a$, a central delta potential of strength $\kappa$ leaves odd parity operator eigenstates unchanged because their wavefunctions vanish at zero. For even states, continuity and the derivative jump ${\psi }^{\prime }(0+)-{\psi }^{\prime }(0-)=2m\kappa \psi (0)/{\hslash }^2$ give the displayed quantization equation. For $\kappa >0$, one root lies between $(n+1/2)\pi /a$ and $(n+1)\pi /a$ for every $n\ge 0$.