Finite-size correction to a variable-site vacancy model

ID: finite-size-correction-to-a-variable-site-vacancy-model

If the variable-site model counts every sector with weight , its exact relative partition sum is . Differentiating its logarithm gives the displayed exact mean. Minimizing the leading extensive Gibbs free energy instead gives , the same result to relative order . Its exact relative equilibrium free energy is . This correction distinguishes a thermodynamic saddle from an exact finite-system average; changing the microscopic site-creation convention can also change subextensive factors.

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