Indirect gap in a uniformly split zone-boundary model

ID: indirect-gap-in-a-uniformly-split-zone-boundary-model

Suppose a model replaces a set of free-electron boundary energies by lower and upper edges and , with . If these are the relevant global band edges, the indirect band gap is , giving the displayed expression. A positive direct gap at each crossing need not be enough: a band insulator needs . This is a band-edge estimate, not a general three-dimensional nearly-free-electron theorem; multiple Bragg planes at a corner can require a larger coupling matrix.

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