Linear Jahn-Teller selection rule

ID: linear-jahn-teller-selection-rule

For a real nonmagnetic electronic multiplet, a vibrational coordinate can couple linearly through a real symmetric electronic operator only if its representation occurs in the symmetric square. Remove the fully symmetric component when asking about symmetry-lowering distortion. In , both and equal , so and modes are symmetry-eligible for either triplet; coupling strengths are not determined by this decomposition.

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