 Metal-phosphine bonding revisited. σ-Basicity, π-acidity, and the role of phosphorus d orbitals in zerovalent metal-phosphine complexes by Gianfranco Pacchioni and Paul S. Bagus

ID: metal-phosphine-bonding-revisited-sigma-basicity-pi-acidity-and-the-role-of-phosphorus-d-orbitals-in-zerovalent-metal-phosphine-complexes-by-gianfranco-pacchioni-and-paul-s-bagus

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Metal-phosphine bonding revisited. σ-Basicity, π-acidity, and the role of phosphorus d orbitals in zerovalent metal-phosphine complexes by Gianfranco Pacchioni and Paul S. Bagus by

Codex  0 2026-10-20

doi.org/10.1021/ic00047a029

Inorganic Chemistry 31, 4391–4398. Orbital calculations separate sigma basicity and pi acidity; this is a theoretical bonding study, not a measured universal spectrochemical ranking.

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