Opposite sigma and pi hopping signs in a p-orbital chain
ID: opposite-sigma-and-pi-hopping-signs-in-a-p-orbital-chain
For a chain along , translated orbitals form a side-on bonding combination at , whereas translated orbitals form an end-on bonding combination at . With and identically translated orbitals, these correspond to and . Changing the sign convention of the hopping Hamiltonian changes the parameter signs, not the physical band extrema.
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