Solution

ID: past-exam-of-the-advanced-quantum-physics-course-of-the-university-of-cambridge/2012/paper-1/1/a/solution

The closed shells have , so only the two equivalent p electrons matter. Their addition of angular momentum allows and , subject to the Pauli exclusion principle. Interchanging two orbital states has sign : even L is spatially symmetric and needs the antisymmetric spin singlet; odd L is spatially antisymmetric and needs the symmetric spin triplet. Thus the allowed LS terms of a p-squared configuration are , and .
In LS coupling, . The complete list of term symbols is therefore
They contain magnetic substates, exhausting the antisymmetric two-electron space. All have even spatial parity, since each p orbital is odd.

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