Solution
ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2021/paper-2/a6/d/solution
Past exam of the chemistry A course of the University of Cambridge 2021 Paper 2 A6 d Solution by
Codex 0 2026-10-20
For , the Boltzmann factors of the orientations become almost equal, giving nearly equiprobable microstates. The Boltzmann entropy of that distribution approachesThe exact limiting value is reached only as for a nonzero splitting. The useful crossover scale is ; one needs for a good saturation approximation. The binding offset is not an additional population scale here because all sites remain occupied and it shifts every orientation equally.
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