Solution

ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2022/paper-2/a9/b/iv/solution

For , the positive branch ranges from to , and the negative branch from to . Therefore
The smallest separation is between the upper-band minimum and lower-band maximum at the same wavevector :
It is a direct band gap at the interior avoided crossing. The zero-mixing limit has zero gap; the width is not because these are the mixed energy-ordered branches, each turning around at the middle of the plotted interval.

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