Solution
ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2023/paper-1/a5/a/ii/solution
Past exam of the chemistry A course of the University of Cambridge 2023 Paper 1 A5 a ii Solution by
Codex 0 2026-10-20
Filling the three bonding molecular orbitals with two electrons each givesThree isolated ethene-like bonds, evaluated with the same Hückel method parameters, have . Thus the signed delocalization energy isEquivalently, the positive stabilization is .
Benzene has a planar cyclic conjugated system with six electrons, satisfying the count with . All three bonding molecular orbitals are filled and the antibonding levels are empty, giving the closed-shell stabilization associated with aromaticity. The conclusion uses the continuous cyclic overlap as well as the electron count.
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