Solution

ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2023/paper-2/a9/b/i/solution

For direct-lattice points , a lattice-periodic plane wave must have the same phase at every translated lattice point:
Thus , with integer , and the reciprocal lattice is
Its spacing is . These plane waves execute an integer number of complete cycles within a direct-lattice period, so their wavelength magnitudes are for .
A general electronic Bloch wave need not itself be lattice-periodic: wavevectors differing by have the same translation phase. The reciprocal lattice labels that equivalence, while a large finite specimen with periodic boundary conditions has a much finer grid of allowed electronic wavevectors.

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