Solution

ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2023/paper-2/a9/b/iv/solution

The first Brillouin zone is the origin-centered Wigner-Seitz cell of the reciprocal lattice. Its nearest reciprocal points are and . The perpendicular bisectors follow from
Consequently the zone is
It is the diamond with vertices
The reciprocal-space sketch above shows these boundaries. Its area is , where . This area check rules out mistakenly using the nonprimitive conventional cell to define a smaller first zone.

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