Solution

ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2024/paper-1/a1/b/i/solution

Set and . The wrapped spatial form is
Hence the differential expression for the quantum rotor acts as
The box expression becomes , so consistency gives
the moment of inertia of a point mass a distance from the axis. Equivalently, transforms the kinetic operator directly. Being an eigenfunction of this differential expression is not yet sufficient: the ring boundary conditions must also hold.
For a wavefunction normalized with the angular measure , use . This change of normalization convention does not change the energy eigenvalue.

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