Solution

ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2024/paper-1/a1/b/ii/solution

A smooth quantum rotor with no flux or twist requires both
For the sine family, holds for every positive integer , but
The derivatives match only for . Equivalently, must be periodic for every , not merely vanish at the chosen join. Odd would produce a cusp in a periodic continuation and do not belong to the smooth free-ring Hamiltonian's domain.

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