Solution

ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2024/paper-1/a1/b/iii/solution

Solving gives an exponential. The periodic boundary condition quantizes its phase winding:
These are normalized with respect to . The corresponding complex Fourier series is
Unlike the wrapped sine subset, this orthonormal basis includes the constant state and both sine and cosine combinations. If one retains arc-length normalization instead, replace by and integrate with .

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