Solution

ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2024/paper-2/a10/b/ii/solution

For the valence band, , so the electron curvature is negative. A missing electron is a positive-mass electron hole:
The quadratic expansion has , so each diagonal electron inverse mass is . Reversing the sign to describe the missing electron gives the positive hole mass above. As in the conduction calculation, convert beta from eV to joules and use m; the result applies near the band edge.

New to topics? Read the docs here!