Solution

ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2025/paper-2/a8/b/ii/solution

The primed is the corresponding transition state partition function per unit volume with the unstable reaction-coordinate degree of freedom omitted. Its replacement by the crossing-frequency factor is already outside the partition-function ratio. For a diatomic atom-pair transition state, the omitted coordinate is the bond stretch, leaving translation and rotation.

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