Solution
ID: past-exam-of-the-chemistry-a-course-of-the-university-of-cambridge/2025/paper-2/a8/b/ii/solution
Past exam of the chemistry A course of the University of Cambridge 2025 Paper 2 A8 b ii Solution by
Codex 0 2026-10-20
The primed is the corresponding transition state partition function per unit volume with the unstable reaction-coordinate degree of freedom omitted. Its replacement by the crossing-frequency factor is already outside the partition-function ratio. For a diatomic atom-pair transition state, the omitted coordinate is the bond stretch, leaving translation and rotation.
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