Solution

ID: past-exam-of-the-chemistry-b-course-of-the-university-of-cambridge/2023/paper-2/b7/b/i/solution

The neutral product is cis-, and the displaced material is six waters per nickel:
The two phosphorus donors of dppe chelate the same metal, forcing adjacent donor positions. The diamagnetism identifies a square-planar, paired Ni(II) centre rather than a tetrahedral high-spin centre. Its valence count is electrons. The reaction is ligand substitution, not reduction of Ni(II).

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