Solution
ID: past-exam-of-the-chemistry-b-course-of-the-university-of-cambridge/2024/paper-2/b6/b/i/solution
Past exam of the chemistry B course of the University of Cambridge 2024 Paper 2 B6 b i Solution by
Codex 0 2026-10-20
Place four terminal trifluorophosphine donors on each cobalt and join the cobalt centers by a single metal-metal bond, as in the first panel. The P atoms bind to cobalt; the fluorines remain attached to phosphorus. Each neutral donor supplies two electrons. Neutral electron counting givesThe ionic description is Co(0), , with eight electrons from the four donors and one from the Co–Co bond. A Co–Co single bond supplies the missing electron at each center. No bridging PF is required by this count.
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