Solution
ID: past-exam-of-the-chemistry-b-course-of-the-university-of-cambridge/2024/paper-2/b6/b/ii/solution
Past exam of the chemistry B course of the University of Cambridge 2024 Paper 2 B6 b ii Solution by
Codex 0 2026-10-20
Use an cyclopentadienyl ligand and four terminal carbonyl ligands at each titanium, with a Ti–Ti single metal-metal bond. The middle panel shows this connectivity. Neutral electron counting assigns five electrons to each Cp and givesEquivalently, the two Cp anions require an average oxidation state Ti(I), hence ; ionic counting gives . The formal Ti–Ti bond order is one. The large coordination envelope can make this bond weak and long; reaching 18 electrons is bookkeeping, rather than proof of a short, strong bond. There is no need to invent extra CO bridges or a higher Ti–Ti bond order.
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