Solution

ID: past-exam-of-the-chemistry-b-course-of-the-university-of-cambridge/2024/paper-2/b6/b/ii/solution

Use an cyclopentadienyl ligand and four terminal carbonyl ligands at each titanium, with a Ti–Ti single metal-metal bond. The middle panel shows this connectivity. Neutral electron counting assigns five electrons to each Cp and gives
Equivalently, the two Cp anions require an average oxidation state Ti(I), hence ; ionic counting gives . The formal Ti–Ti bond order is one. The large coordination envelope can make this bond weak and long; reaching 18 electrons is bookkeeping, rather than proof of a short, strong bond. There is no need to invent extra CO bridges or a higher Ti–Ti bond order.

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