Solution
ID: past-exam-of-the-chemistry-b-course-of-the-university-of-cambridge/2025/paper-1/b4/b/ii/solution
Past exam of the chemistry B course of the University of Cambridge 2025 Paper 1 B4 b ii Solution by
Codex 0 2026-10-20
The diagnostic feature is the large vicinal coupling characteristic of an axial–axial relationship in a chair. The td patterns for and contain two large couplings to neighbouring axial hydrogens, so both are axial. The ddd patterns for and also include a large ring vicinal coupling, with the smaller values reflecting the other ring hydrogen and the side chain. The assignments areThe chemical shifts alone do not determine this assignment. In particular, three unequal splittings of a methine are not a geminal-coupling pattern.
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