Solution

ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2021/paper-1/10/c/ii/solution

Water is the preferred solvent ligand in the qualitative prediction. Its oxygen is a hard donor, it is less sterically demanding than ethanol, and it can occupy a crowded Eu(III) coordination sphere. Actual solvent occupancy also depends on activities and crystallization conditions, so a formula containing only the word solvent is not itself a crystallographic identification.

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