Solution
ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2021/paper-1/9/b/ii/solution
Past exam of the chemistry course of the year 3 of the natural sciences course of the University of Cambridge 2021 Paper 1 9 b ii Solution by
Codex 0 2026-10-20
For a neutral borane with one terminal B–H bond assigned to each vertex, the skeletal electron number is ; an overall charge adds electrons. Suitable twelve-electron correspondences areFor C, four BH contributions plus four additional hydrogens give electrons. For D, three BH contributions plus five additional hydrogens and the negative charge give . They map to the tetrahedral and triangular low-vertex skeletons respectively. The neutral formal alternative for D is , also with twelve skeletal electrons.
The electron counting correspondence alone must not be read as evidence that the neutral boranes are isolable stable bulk materials. Low-vertex hydrogen-rich boranes can be transient; the triangular octahydrotriborate anion is the established practical three-boron example, whereas neutral is a formal analogy rather than an equally established preparative product. The requested skeletal correspondence should be distinguished from a claim about comparable stability or isolation conditions.[ref]
Reactions of the octahydrotriborate(1-) anion, B3H8-, with some complexes of cobalt(I), cobalt(II), rhodium(I), and iridium(I), and the characterization of the borallyl complex IrIII(eta3-B3H7)(CO)H(PPh3)2 by Norman N. Greenwood and others. 1980, pp.196–200, reactions of the preparatively accessible octahydrotriborate anion
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