Solution

ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2021/paper-2a/section-b/21/a/iv/solution

The square-planar rotor is an oblate symmetric top. A parallel band has and , producing P and R progressions with approximate spacing and a central Q contribution from ; the parallel Q branch is absent. At modest resolution many nearly coincident components merge.
A perpendicular band has and . Its Q subbranches produce a characteristic series of sharper features on the broader unresolved P/R envelope. Neglecting changes of rotational constants on vibration, successive perpendicular Q features are separated by approximately . These are rotational contours rather than extra normal-mode fundamentals.

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