Solution

ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2021/paper-2a/section-b/22/c/solution

The measured decay is approximately consistent with the predicted loss rate. Following rapid singlet-to-triplet population transfer, the unquenched phosphorescence intensity obeys
A straight-line fit of to the four times, expressed in seconds, gives
This differs from by about . For example, using the first point and the predicted rate gives subsequent intensities about , close to the supplied . The data support the expected millisecond exponential decay to this precision. With no measurement uncertainties supplied, a formal statistical acceptance or rejection is not justified.

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