Solution
ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-2a/section-b/21/a/iii/solution
Past exam of the chemistry course of the year 3 of the natural sciences course of the University of Cambridge 2022 Paper 2A Section B 21 a iii Solution by
Codex 0 2026-10-20
A spectral component shifts by the difference between its upper- and lower-level Stark shifts. With , and , the supplied energy formula givesFor radiation polarized parallel to the static field, , soThus the assigned feature has no first-order splitting, whereas the features acquire symmetrically arranged magnetic-sublevel components with spacings proportional to . With perpendicular radiation, gives the corresponding different allowed pattern. Recording field-dependent spectra with specified polarization would test both the J values and the K sequence; using an individual level's shift alone would not predict the observed line positions. Higher-order shifts of the nominally unsplit feature are outside this first-order test.
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